TY - JOUR
T1 - A photocatalytic cycle for mild oxidation by dioxygen of substrates easily oxidizable by iodine
AU - Figueiredo, Paulo
AU - Pina, Fernando
N1 - Funding Information:
Financial support from Instituto National de gratefully acknowledged.
PY - 1988/7
Y1 - 1988/7
N2 - A photocatalytic cycle based on the ion pair Co(sep)3+·I- (sep sepulchrate 1,3,6,8,10,13,16,19-octaazabicyclo[6.6.6] eicosane)), in which substrates easily oxidizable by iodine are oxidized by dioxygen, is described. A direct relation between the ion pair charge transfer band maximum and the one-electron redox potential of the corresponding anion was verified. Possible applications of these cycles, such as energy conversion, are discussed.
AB - A photocatalytic cycle based on the ion pair Co(sep)3+·I- (sep sepulchrate 1,3,6,8,10,13,16,19-octaazabicyclo[6.6.6] eicosane)), in which substrates easily oxidizable by iodine are oxidized by dioxygen, is described. A direct relation between the ion pair charge transfer band maximum and the one-electron redox potential of the corresponding anion was verified. Possible applications of these cycles, such as energy conversion, are discussed.
UR - http://www.scopus.com/inward/record.url?scp=50849145596&partnerID=8YFLogxK
U2 - 10.1016/1010-6030(88)85005-6
DO - 10.1016/1010-6030(88)85005-6
M3 - Article
AN - SCOPUS:50849145596
VL - 44
SP - 57
EP - 61
JO - Journal of Photochemistry and Photobiology A: Chemistry
JF - Journal of Photochemistry and Photobiology A: Chemistry
SN - 1010-6030
IS - 1
ER -