@article{d33c7ff6e4e94851b231be4beeef84d1,
title = "A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica",
abstract = "The first lanthanopolyoxometalate-supported bifunctional periodic mesoporous organosilica (BPMO) composite is here reported. The incorporation of decatunsgstoeuropate anions ([Eu(W5O18)2]9−) within the porous channels of an ethylene-bridged TMAPS-functionalized BPMO produced a luminescent material exhibiting a strong red emission under UV irradiation. Photoluminescence studies showed an efficient energy transfer process to the lanthanide emitting center in the material (antenna effect). A significant change in the coordination environment of Eu3+ ions was observed after its incorporation into the TMAPS-functionalized material. The possible reason for this is discussed within the paper.",
keywords = "Polyoxometalate, Mesoporous silica, Composite, Luminescence, Lanthanide",
author = "Granadeiro, {Carlos M.} and Ribeiro, {Susana O.} and Kaczmarek, {Anna M.} and Lu{\'i}s Cunha-Silva and Almeida, {Pedro L.} and Sandra Gago and {Van Deun}, Rik and {de Castro}, Baltazar and Balula, {Salete S.}",
note = "Sem PDF. info:eu-repo/grantAgreement/FCT/5876/147218/PT# info:eu-repo/grantAgreement/FCT/5876/147333/PT# info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F73191%2F2010/PT# info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBD%2F95571%2F2013/PT# Associate Laboratory Research Unit for Green Chemistry - Technologies and Processes Clean - LAQV National Funds from FCT/MEC (UID/QUI/50006/2013) ERDF under the PT Partnership Agreement (POCI-01-0145-FEDER - 007265) CENIMAT (3N (UID/CTM/50025/2013) Portuguese Nuclear Magnetic Resonance Network (PTNMR) Ghent University's Special Research Fund (BOF) for a Postdoctoral Mandate BOF15/PDO/091 Hercules Foundation (AUGE/09/024) (SFRH/BPD/73191/2010; SFRH/BPD/111168/2015; SFRH/BD/95571/2013) ",
year = "2016",
month = nov,
day = "1",
doi = "10.1016/j.micromeso.2016.07.023",
language = "English",
volume = "234",
pages = "248--256",
journal = "Microporous and Mesoporous Materials",
issn = "1387-1811",
publisher = "Elsevier Science B.V., Inc",
}